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- W2111561807 abstract "Tertiary 1-naphthamides racemise much more slowly than their laterally lithiated derivatives, and the relative rates of racemisation and epimerisation of these derivatives indicate that the lithium-bearing stereogenic centre inverts via a “conducted tour” mechanism, in which the lithium cation is delivered from one face to the other by coordination to the rotating amide group." @default.
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- W2111561807 date "2004-01-01" @default.
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- W2111561807 title "Fast racemisation and slow epimerisation of laterally lithiated amides: stereochemical evidence for the mechanism of inversion of amide-substituted benzyllithiums" @default.
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- W2111561807 doi "https://doi.org/10.1039/b310963a" @default.
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