Matches in SemOpenAlex for { <https://semopenalex.org/work/W2111597530> ?p ?o ?g. }
- W2111597530 abstract "[539-80-0] C7H6O (MW 106.13) InChI = 1S/C7H6O/c8-7-5-3-1-2-4-6-7/h1-6H InChIKey = QVWDCTQRORVHHT-UHFFFAOYSA-N (synthon for preparation of cycloheptadien-1-ones; building block in the synthesis of troponoids, azulenes,1a,b polycyclic compounds,1c,d natural products1d,e) Alternate Name: tropone. Physical Data: mp −8 °C to −5 °C; bp 113 °C/15 mmHg; d422 1.10 g cm−3; n22D 1.6172. Solubility: sol ether, dioxane, acetone, benzene, toluene, xylene, MeCN, CCl4; miscible with water. Preparative Methods: 2,4,6-cycloheptatrien-1-one 1 is a functionalized conjugated carbocyclic compound with diversified reactivity. The most popular and simple method of preparation involves oxidation of 1,3,5‐Cycloheptatriene with Selenium(IV) Oxide–KH2PO4.2a Several other procedures have also been developed,2b– among which electrooxidation of cycloheptatrienes2e and α-pyrone ring expansion via high-pressure cycloaddition of cyclopropenone acetals2f can be considered general methods of synthesis of tropones. Purification: by distillation. Analysis of Reagent Purity: 1H NMR, GLC. Handling, Storage, and Precautions: light- and oxidant-sensitive." @default.
- W2111597530 created "2016-06-24" @default.
- W2111597530 creator A5024961412 @default.
- W2111597530 date "2001-04-15" @default.
- W2111597530 modified "2023-09-25" @default.
- W2111597530 title "2,4,6-Cycloheptatrien-1-one" @default.
- W2111597530 cites W1568518637 @default.
- W2111597530 cites W1964982940 @default.
- W2111597530 cites W1966121707 @default.
- W2111597530 cites W1967660128 @default.
- W2111597530 cites W1969395175 @default.
- W2111597530 cites W1975069964 @default.
- W2111597530 cites W1980069623 @default.
- W2111597530 cites W1980228913 @default.
- W2111597530 cites W1980617716 @default.
- W2111597530 cites W1981550684 @default.
- W2111597530 cites W1997728224 @default.
- W2111597530 cites W1999935029 @default.
- W2111597530 cites W2005996587 @default.
- W2111597530 cites W2007072617 @default.
- W2111597530 cites W2011460222 @default.
- W2111597530 cites W2013940643 @default.
- W2111597530 cites W2017879276 @default.
- W2111597530 cites W2018000996 @default.
- W2111597530 cites W2019265462 @default.
- W2111597530 cites W2021493628 @default.
- W2111597530 cites W2031262221 @default.
- W2111597530 cites W2032536629 @default.
- W2111597530 cites W2033089590 @default.
- W2111597530 cites W2033945937 @default.
- W2111597530 cites W2035311011 @default.
- W2111597530 cites W2042350102 @default.
- W2111597530 cites W2042528744 @default.
- W2111597530 cites W2044734052 @default.
- W2111597530 cites W2046839557 @default.
- W2111597530 cites W2053147469 @default.
- W2111597530 cites W2058335119 @default.
- W2111597530 cites W2075821440 @default.
- W2111597530 cites W2079052906 @default.
- W2111597530 cites W2082466195 @default.
- W2111597530 cites W2087615308 @default.
- W2111597530 cites W2088766305 @default.
- W2111597530 cites W2089187520 @default.
- W2111597530 cites W2091869171 @default.
- W2111597530 cites W2093663051 @default.
- W2111597530 cites W2106016877 @default.
- W2111597530 cites W2126190996 @default.
- W2111597530 cites W2166229590 @default.
- W2111597530 cites W2323431832 @default.
- W2111597530 cites W2331771164 @default.
- W2111597530 cites W2331958599 @default.
- W2111597530 cites W2344723899 @default.
- W2111597530 cites W2360403184 @default.
- W2111597530 cites W2949123592 @default.
- W2111597530 cites W2949130065 @default.
- W2111597530 cites W2950345131 @default.
- W2111597530 cites W2951841838 @default.
- W2111597530 cites W2952036802 @default.
- W2111597530 cites W2952733191 @default.
- W2111597530 cites W3004921078 @default.
- W2111597530 cites W1978927009 @default.
- W2111597530 doi "https://doi.org/10.1002/047084289x.rc280" @default.
- W2111597530 hasPublicationYear "2001" @default.
- W2111597530 type Work @default.
- W2111597530 sameAs 2111597530 @default.
- W2111597530 citedByCount "0" @default.
- W2111597530 crossrefType "reference-entry" @default.
- W2111597530 hasAuthorship W2111597530A5024961412 @default.
- W2111597530 hasConcept C155574463 @default.
- W2111597530 hasConcept C155647269 @default.
- W2111597530 hasConcept C161790260 @default.
- W2111597530 hasConcept C178790620 @default.
- W2111597530 hasConcept C185592680 @default.
- W2111597530 hasConcept C2776219776 @default.
- W2111597530 hasConcept C2778142098 @default.
- W2111597530 hasConcept C2779023668 @default.
- W2111597530 hasConcept C2779664164 @default.
- W2111597530 hasConcept C2779896714 @default.
- W2111597530 hasConcept C2780407432 @default.
- W2111597530 hasConcept C40869318 @default.
- W2111597530 hasConcept C40875361 @default.
- W2111597530 hasConceptScore W2111597530C155574463 @default.
- W2111597530 hasConceptScore W2111597530C155647269 @default.
- W2111597530 hasConceptScore W2111597530C161790260 @default.
- W2111597530 hasConceptScore W2111597530C178790620 @default.
- W2111597530 hasConceptScore W2111597530C185592680 @default.
- W2111597530 hasConceptScore W2111597530C2776219776 @default.
- W2111597530 hasConceptScore W2111597530C2778142098 @default.
- W2111597530 hasConceptScore W2111597530C2779023668 @default.
- W2111597530 hasConceptScore W2111597530C2779664164 @default.
- W2111597530 hasConceptScore W2111597530C2779896714 @default.
- W2111597530 hasConceptScore W2111597530C2780407432 @default.
- W2111597530 hasConceptScore W2111597530C40869318 @default.
- W2111597530 hasConceptScore W2111597530C40875361 @default.
- W2111597530 hasLocation W21115975301 @default.
- W2111597530 hasOpenAccess W2111597530 @default.
- W2111597530 hasPrimaryLocation W21115975301 @default.
- W2111597530 hasRelatedWork W2067059319 @default.
- W2111597530 hasRelatedWork W2069358476 @default.
- W2111597530 hasRelatedWork W2111597530 @default.