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- W2111650168 abstract "Quaternary stereocenters are obtained at room temperature in copper-catalyzed asymmetric Michael reactions with α-amino acid amides as chiral auxiliaries. L-Valine diethylamide was applied as a chiral auxiliary, and an optically active piperidine derivative was prepared with 97% ee. The optical purity of the product was established by GLC after cyclization to a hexahydroisoquinolonecarboxylate. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2111650168 date "2002-05-01" @default.
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- W2111650168 title "Copper-Catalyzed Asymmetric Michael Reactions with α-Amino Acid Amides: Synthesis of an Optically Active Piperidine Derivative" @default.
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- W2111650168 doi "https://doi.org/10.1002/1099-0690(200205)2002:9<1505::aid-ejoc1505>3.0.co;2-k" @default.
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