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- W2111663241 abstract "Abstract Na/Pb alloy reduction of the (perfluoroisopropyl)iridium complex Cp*(CO)IrI[CF(CF 3 ) 2 ] afforded the first example of a bis(trifluoromethyl)carbene complex, Cp*(CO)Ir=C(CF 3 ) 2 , which has been crystallographically characterized. Further reduction of this carbene complex with KC 8 yielded the perfluoroallene iridium complex Cp*Ir(CO)(η 2 ‐CF 2 CCF 2 ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2111663241 date "2007-10-01" @default.
- W2111663241 modified "2023-09-24" @default.
- W2111663241 title "The First Example of a Bis(trifluoromethyl)carbene Transition‐Metal Complex and Its Reduction to a Perfluoroallene Complex" @default.
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- W2111663241 doi "https://doi.org/10.1002/ejic.200700814" @default.
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