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- W2111707240 abstract "2-Substituted indoles (5a,b and 7) and fused indoles (9a-c, 11a,b, and 12) have been obtained by the S(RN)1 mechanism from photostimulated reactions of o-iodoaniline (1) and 1-halo-2-naphthalen-2-ylamines (3a,b) with enolate ions of acyclic (acetophenone (6), 2- (4a) and 4-acetylpyridine (4b)) and cyclic ketones (1- (8a) and 2-indanone (10a), 1- (8b) and 2-tetralone (10b) and 1-benzosuberone (8c)) in DMSO and liquid ammonia as solvents. The carbanions derived from 4a,b, 8a, and 10b are novel nucleophiles that form new C-C bonds by the S(RN)1 mechanism." @default.
- W2111707240 created "2016-06-24" @default.
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- W2111707240 date "2003-03-04" @default.
- W2111707240 modified "2023-10-16" @default.
- W2111707240 title "Syntheses of 2-Substituted Indoles and Fused Indoles by Photostimulated Reactions of <i>o</i>-Iodoanilines with Carbanions by the S<sub>RN</sub>1 Mechanism" @default.
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- W2111707240 doi "https://doi.org/10.1021/jo026672k" @default.
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