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- W2111712076 abstract "The redox systems [(NC)5Fe(μ-L)Fe(CN)5])6−/5−/4− with L=pyrazine (1n), 4,4′-bipyridine (2n) or 1,2-bis(4-pyridyl)ethene (3n), and [(NC)4Fe(μ-bmtz)Fe(CN)4]5−/4−/3− (4n) with bmtz=3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine were studied in acetonitrile and other aprotic solvents. The comproportionation constants Kc for the mixed-valent diiron(III, II) intermediates vary from less than 10 for 35− via 106.5 for 15− to 1014.1 for 43−. Intervalence charge transfer band maxima lie between 1270 nm (25−) and 2475 nm (15−). In comparison with previous results from aqueous solutions, the system 1n in particular shows increased metal–metal interaction. UV–Vis and IR spectroelectrochemistry suggest a localized/delocalized borderline sitation for 15− in acetonitrile, with only slightly weaker metal–metal coupling than in the related Creutz–Taube ion. The results illustrate how the established strong solvent sensitivity of cyanoiron complexes can be exploited in mixed-valence chemistry." @default.
- W2111712076 created "2016-06-24" @default.
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- W2111712076 date "1999-08-01" @default.
- W2111712076 modified "2023-10-16" @default.
- W2111712076 title "Widely differing stabilities of molecule-bridged cyanodiiron(III,II) species in non-aqueous solvents" @default.
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- W2111712076 doi "https://doi.org/10.1016/s0020-1693(99)00039-0" @default.
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