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• W2111785934 abstract "The existence of isostructural titanates with a composition corresponding to the formula MLi2Ti6O14 has been evidenced in the ternary oxide systems MO–Li2O–TiO2 (M = Sr, Ba, Pb). Single crystals of these compounds have been grown by the flux method using LiBO2 as a high-temperature solvent. The structure, as determined by single crystal X-ray diffraction is orthorhombic (space group Cmca (no. 64), Z = 8) with (i) a = 16.570(5) Å, b = 11.150(2) Å, c = 11.458(2) Å, V = 2116.9(8) Å3, R1 = 0.039, wR2 = 0.087 for SrLi2Ti6O14; (ii) a = 16.577(1) Å, b = 11.273(1) Å, c = 11.581(1) Å, V = 2164.2(5) Å3, R1 = 0.018, wR2 = 0.047 for BaLi2Ti6O14 and (iii) a = 16.649(1) Å, b = 11.146(1) Å, c = 11.494(1) Å, V = 2132.9(5) Å3, R1 = 0.033, wR2 = 0.078 for PbLi2Ti6O14. A three-dimensional framework of edge and corner sharing TiO6 octahedra sets up the crystal structure. Lithium occupies the tetrahedral vacancies, while M atoms are located at 11-oxygen coordinated sites." @default.
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• W2111785934 date "2005-03-01" @default.
• W2111785934 modified "2023-09-30" @default.
• W2111785934 title "A new family of isostructural titanates, MLi2Ti6O14 (M = Sr, Ba, Pb)" @default.
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• W2111785934 doi "https://doi.org/10.1016/j.jallcom.2004.08.026" @default.
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