Matches in SemOpenAlex for { <https://semopenalex.org/work/W2111823896> ?p ?o ?g. }
- W2111823896 endingPage "1072" @default.
- W2111823896 startingPage "1060" @default.
- W2111823896 abstract "The IVCT characteristics of the mixed valence forms of the trinuclear complex [{Δ-Ru(bpy)2}2{Δt-Ru(bpy)(µ-ppz)2}]n+ (n = 7, 8; t = trans), and the diastereoisomers (meso and rac) of the dinuclear complex [{Ru(bpy)2}2(µ-ppz)]5+, display a marked dependence on the nuclearity and extent of oxidation of the assemblies. The dinuclear species are classified as borderline localised–delocalised mixed valence species while the two mixed valence states of the trinuclear complex exhibit localised behaviour. One-electron oxidation of a terminal Ru centre in the trinuclear case gives rise to a broad, low intensity IVCT band for the +7 mixed valence species which is composed of two underlying Gaussian-shaped bands. The transitions are identified as adjacent and remote IVCT transitions, with the former dominating the intensity of the IVCT manifold. The +8 mixed valence species exhibits a single dominant IVCT band arising from the equivalent IVCT transitions from the central RuII to peripheral RuIII centres." @default.
- W2111823896 created "2016-06-24" @default.
- W2111823896 creator A5003296253 @default.
- W2111823896 creator A5037511547 @default.
- W2111823896 date "2006-01-01" @default.
- W2111823896 modified "2023-10-14" @default.
- W2111823896 title "Intervalence charge transfer in a “chain-like” ruthenium trinuclear assembly based on the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine (ppz)" @default.
- W2111823896 cites W1691067281 @default.
- W2111823896 cites W1963567221 @default.
- W2111823896 cites W1966377407 @default.
- W2111823896 cites W1967895364 @default.
- W2111823896 cites W1969713159 @default.
- W2111823896 cites W1970451057 @default.
- W2111823896 cites W1971731306 @default.
- W2111823896 cites W1973959585 @default.
- W2111823896 cites W1977048541 @default.
- W2111823896 cites W1979968163 @default.
- W2111823896 cites W1980307068 @default.
- W2111823896 cites W1983069329 @default.
- W2111823896 cites W1985909627 @default.
- W2111823896 cites W1986586041 @default.
- W2111823896 cites W1987583072 @default.
- W2111823896 cites W1991725845 @default.
- W2111823896 cites W1995684877 @default.
- W2111823896 cites W2001478989 @default.
- W2111823896 cites W2005268958 @default.
- W2111823896 cites W2006222872 @default.
- W2111823896 cites W2014499171 @default.
- W2111823896 cites W2014628294 @default.
- W2111823896 cites W2017448072 @default.
- W2111823896 cites W2018702761 @default.
- W2111823896 cites W2022322814 @default.
- W2111823896 cites W2025880576 @default.
- W2111823896 cites W2026454474 @default.
- W2111823896 cites W2028566606 @default.
- W2111823896 cites W2029452534 @default.
- W2111823896 cites W2034046916 @default.
- W2111823896 cites W2036528722 @default.
- W2111823896 cites W2039818789 @default.
- W2111823896 cites W2039906595 @default.
- W2111823896 cites W2042501369 @default.
- W2111823896 cites W2045512386 @default.
- W2111823896 cites W2047054738 @default.
- W2111823896 cites W2048039782 @default.
- W2111823896 cites W2048262633 @default.
- W2111823896 cites W2050952238 @default.
- W2111823896 cites W2051502181 @default.
- W2111823896 cites W2052752040 @default.
- W2111823896 cites W2053974085 @default.
- W2111823896 cites W2057820608 @default.
- W2111823896 cites W2058135545 @default.
- W2111823896 cites W2059693385 @default.
- W2111823896 cites W2065303303 @default.
- W2111823896 cites W2072545091 @default.
- W2111823896 cites W2078141919 @default.
- W2111823896 cites W2079996883 @default.
- W2111823896 cites W2084866980 @default.
- W2111823896 cites W2090190871 @default.
- W2111823896 cites W2091272560 @default.
- W2111823896 cites W2091728522 @default.
- W2111823896 cites W2091807666 @default.
- W2111823896 cites W2092684467 @default.
- W2111823896 cites W2105510993 @default.
- W2111823896 cites W2113813397 @default.
- W2111823896 cites W2120085385 @default.
- W2111823896 cites W2160737217 @default.
- W2111823896 cites W2163237642 @default.
- W2111823896 cites W254452716 @default.
- W2111823896 cites W29179573 @default.
- W2111823896 cites W2949976919 @default.
- W2111823896 cites W2950531917 @default.
- W2111823896 cites W2951571121 @default.
- W2111823896 cites W2951972926 @default.
- W2111823896 cites W3139454697 @default.
- W2111823896 cites W3140868725 @default.
- W2111823896 cites W4253345845 @default.
- W2111823896 doi "https://doi.org/10.1039/b512625h" @default.
- W2111823896 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16474892" @default.
- W2111823896 hasPublicationYear "2006" @default.
- W2111823896 type Work @default.
- W2111823896 sameAs 2111823896 @default.
- W2111823896 citedByCount "14" @default.
- W2111823896 countsByYear W21118238962014 @default.
- W2111823896 countsByYear W21118238962016 @default.
- W2111823896 countsByYear W21118238962017 @default.
- W2111823896 countsByYear W21118238962018 @default.
- W2111823896 countsByYear W21118238962022 @default.
- W2111823896 countsByYear W21118238962023 @default.
- W2111823896 crossrefType "journal-article" @default.
- W2111823896 hasAuthorship W2111823896A5003296253 @default.
- W2111823896 hasAuthorship W2111823896A5037511547 @default.
- W2111823896 hasConcept C115624301 @default.
- W2111823896 hasConcept C138716334 @default.
- W2111823896 hasConcept C161790260 @default.
- W2111823896 hasConcept C168900304 @default.
- W2111823896 hasConcept C178790620 @default.
- W2111823896 hasConcept C185592680 @default.
- W2111823896 hasConcept C2777765701 @default.