Matches in SemOpenAlex for { <https://semopenalex.org/work/W2111838815> ?p ?o ?g. }
- W2111838815 endingPage "157" @default.
- W2111838815 startingPage "157" @default.
- W2111838815 abstract "The effects of borate buffers on the pseudo first-order rate constants for the hydration of hydroxyacetonitrile (1) have been examined in the pH range 8.6–10.3 at 80 °C. Kinetic results are compatible with a reaction of the neutral cyanohydrin with borate anion or any other kinetically equivalent mechanism. Cyanohydrin structural effects are consistent with a pathway involving the pre-equilibrium formation of a borate–substrate adduct, followed by a rate-determining intramolecular nucleophihc attack on the nitrile group. Phenylboronate ion has also been shown to act as an efficient catalyst, but it was not possible to detect any influence due to disubstituted borate ions. Thus, it is suggested that a trigonal borate anion actually acts as a nucleophile." @default.
- W2111838815 created "2016-06-24" @default.
- W2111838815 creator A5070943204 @default.
- W2111838815 creator A5080336333 @default.
- W2111838815 creator A5084045253 @default.
- W2111838815 date "1990-01-01" @default.
- W2111838815 modified "2023-10-18" @default.
- W2111838815 title "The influence of borate buffers on the hydration rate of cyanohydrins: evidence for an intramolecular mechanism" @default.
- W2111838815 cites W1022309144 @default.
- W2111838815 cites W1967028328 @default.
- W2111838815 cites W1967306571 @default.
- W2111838815 cites W1976301859 @default.
- W2111838815 cites W1979939682 @default.
- W2111838815 cites W1979990692 @default.
- W2111838815 cites W1991939742 @default.
- W2111838815 cites W1992953641 @default.
- W2111838815 cites W2004284474 @default.
- W2111838815 cites W2004840733 @default.
- W2111838815 cites W2006058161 @default.
- W2111838815 cites W2011259638 @default.
- W2111838815 cites W2022140467 @default.
- W2111838815 cites W2030374057 @default.
- W2111838815 cites W2033354208 @default.
- W2111838815 cites W2033931864 @default.
- W2111838815 cites W2040857113 @default.
- W2111838815 cites W2041838414 @default.
- W2111838815 cites W2045612588 @default.
- W2111838815 cites W2054732953 @default.
- W2111838815 cites W2055940846 @default.
- W2111838815 cites W2064154280 @default.
- W2111838815 cites W2098594840 @default.
- W2111838815 cites W2147459677 @default.
- W2111838815 cites W2152649528 @default.
- W2111838815 cites W2318275731 @default.
- W2111838815 cites W2323963387 @default.
- W2111838815 cites W2325761731 @default.
- W2111838815 cites W2328552250 @default.
- W2111838815 cites W2332811554 @default.
- W2111838815 cites W2333046663 @default.
- W2111838815 cites W2334442702 @default.
- W2111838815 cites W241063502 @default.
- W2111838815 cites W3004486953 @default.
- W2111838815 cites W3005321230 @default.
- W2111838815 cites W3005324165 @default.
- W2111838815 cites W3024413468 @default.
- W2111838815 cites W2027176774 @default.
- W2111838815 doi "https://doi.org/10.1039/p29900000157" @default.
- W2111838815 hasPublicationYear "1990" @default.
- W2111838815 type Work @default.
- W2111838815 sameAs 2111838815 @default.
- W2111838815 citedByCount "13" @default.
- W2111838815 countsByYear W21118388152013 @default.
- W2111838815 countsByYear W21118388152017 @default.
- W2111838815 countsByYear W21118388152019 @default.
- W2111838815 countsByYear W21118388152021 @default.
- W2111838815 crossrefType "journal-article" @default.
- W2111838815 hasAuthorship W2111838815A5070943204 @default.
- W2111838815 hasAuthorship W2111838815A5080336333 @default.
- W2111838815 hasAuthorship W2111838815A5084045253 @default.
- W2111838815 hasConcept C108204754 @default.
- W2111838815 hasConcept C111368507 @default.
- W2111838815 hasConcept C121332964 @default.
- W2111838815 hasConcept C127313418 @default.
- W2111838815 hasConcept C145148216 @default.
- W2111838815 hasConcept C148898269 @default.
- W2111838815 hasConcept C155647269 @default.
- W2111838815 hasConcept C161790260 @default.
- W2111838815 hasConcept C178790620 @default.
- W2111838815 hasConcept C178907741 @default.
- W2111838815 hasConcept C179104552 @default.
- W2111838815 hasConcept C185592680 @default.
- W2111838815 hasConcept C2777289219 @default.
- W2111838815 hasConcept C2778910044 @default.
- W2111838815 hasConcept C2779240715 @default.
- W2111838815 hasConcept C501308230 @default.
- W2111838815 hasConcept C62520636 @default.
- W2111838815 hasConcept C71240020 @default.
- W2111838815 hasConcept C75079739 @default.
- W2111838815 hasConcept C75473681 @default.
- W2111838815 hasConcept C93391505 @default.
- W2111838815 hasConceptScore W2111838815C108204754 @default.
- W2111838815 hasConceptScore W2111838815C111368507 @default.
- W2111838815 hasConceptScore W2111838815C121332964 @default.
- W2111838815 hasConceptScore W2111838815C127313418 @default.
- W2111838815 hasConceptScore W2111838815C145148216 @default.
- W2111838815 hasConceptScore W2111838815C148898269 @default.
- W2111838815 hasConceptScore W2111838815C155647269 @default.
- W2111838815 hasConceptScore W2111838815C161790260 @default.
- W2111838815 hasConceptScore W2111838815C178790620 @default.
- W2111838815 hasConceptScore W2111838815C178907741 @default.
- W2111838815 hasConceptScore W2111838815C179104552 @default.
- W2111838815 hasConceptScore W2111838815C185592680 @default.
- W2111838815 hasConceptScore W2111838815C2777289219 @default.
- W2111838815 hasConceptScore W2111838815C2778910044 @default.
- W2111838815 hasConceptScore W2111838815C2779240715 @default.
- W2111838815 hasConceptScore W2111838815C501308230 @default.
- W2111838815 hasConceptScore W2111838815C62520636 @default.
- W2111838815 hasConceptScore W2111838815C71240020 @default.