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- W2111923712 abstract "Dimethyl acetylenedicarboxylate reacts with 7-dehydrocholesteryl acetate (I) by nucleophilic addition at C7. Two products are obtained, resulting from subsequent hydrogen abstraction from C9 (II) and from C14 (III) respectively. Addition-abstraction, hitherto unreported for esters of acetylenedicarboxylic acid, appears to be the sole reaction mode with this highly hindered diene-system. Structure proof is supported by NMR spectroscopy as well as by chemical transformations of the adducts. On treatment with base one of the adducts undergoes a prototropic rearrangement." @default.
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- W2111923712 date "1965-01-01" @default.
- W2111923712 modified "2023-09-23" @default.
- W2111923712 title "Addition to steroid polyenes—II" @default.
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- W2111923712 doi "https://doi.org/10.1016/s0040-4020(01)96979-0" @default.
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