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- W2112151294 abstract "The derivation of the intensities of rotation and rotation-vibration Raman transitions for asymmetric top molecules is given, based on irreducible spherical tensor formalism. A computer program package written to calculate such intensities is described. Its use is demonstrated by reproducing the observed contours of the pure rotational band and the asymmetric stretching vibrational band in the Raman spectrum of the SO2 molecule. The polarizability tensor component ratio required to simulate the pure rotational contour is combined with literature values for mean polarizability and depolarization ratio to obtain the principal values of the SO2 polarizability tensor. A correlation of the polarizability tensor component ratio with band types is discussed for totally symmetric bands which have been reproduced using our program and those of others." @default.
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- W2112151294 date "1981-10-01" @default.
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- W2112151294 title "Intensities of rotation and vibration-rotation Raman transitions in asymmetric top molecules" @default.
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- W2112151294 doi "https://doi.org/10.1002/jrs.1250110510" @default.
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