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- W2112319507 abstract "Abstract Two new dinuclear copper(II) metallacyclophanes with 1,4‐disubstituted 9,10‐anthraquinonebis(oxamate) bridging ligands are reported that can reversibly take and release electrons at the redox‐active ligand and metal sites, respectively, to give the corresponding mono‐ and bis(semiquinonate and/or catecholate) Cu II 2 species and mixed‐valent Cu II /Cu III and high‐valent Cu III 2 ones. Density functional calculations allow us to give further insights on the dual ligand‐ and metal‐based character of the redox processes in this novel family of antiferromagnetically coupled di‐ copper(II) anthraquinophanes. This unique ability for charge storage could be the basis for the development of new kinds of molecular spintronic devices, referred to as molecular magnetic capacitors (MMCs)." @default.
- W2112319507 created "2016-06-24" @default.
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- W2112319507 date "2014-09-11" @default.
- W2112319507 modified "2023-10-17" @default.
- W2112319507 title "Dicopper(II) Anthraquinophanes as Multielectron Reservoirs for Oxidation and Reduction: A Joint Experimental and Theoretical Study" @default.
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- W2112319507 doi "https://doi.org/10.1002/chem.201403987" @default.
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