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- W2112425365 abstract "Abstract 1- O -Benzylpentitols (with d - arabino , d - lyxo , d , l - xylo and d , l - ribo configurations) and aldoses dibenzyldithioacetals (with l - arabino , d - lyxo , d - xylo , d - ribo , d - galacto , d - gluco and d - manno configurations) were directly and efficiently transformed into their cyclic bis-thionocarbonate derivatives (61–73%) by reaction with diimidazolyl thione (Im 2 CS) in 1,4-dioxane. These bis-electrophilic adducts react regioselectively with Na 2 S·9H 2 O or Se/NaBH 4 to lead regioselectively to the corresponding thiolane and selenolane rings in good yields for a short synthesis (47–65%)." @default.
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- W2112425365 date "2005-07-01" @default.
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- W2112425365 title "Short synthesis of hydroxylated thiolane and selenolane rings from mono-benzylated pentitols and aldoses dithioacetals bis-thionocarbonates as bis-electrophilic substrates" @default.
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- W2112425365 doi "https://doi.org/10.1016/j.tet.2005.05.008" @default.
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