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- W2112462021 abstract "Solvent polarity is a subject of great interest to chemists. A significant component of a solvent's polarity is its capacity for nonspecific electrostatic interactions, which is often parameterized using the dielectric constant ε or the Kamlet–Taft dipolarity/polarizability parameter π*. Recent theoretical work has established a connection between the molar volume of an ionic liquid and its capacity for nonspecific electrostatic interactions with a neutral dipolar solute. In this work, we make use of a recently-developed theoretical method to estimate the molar volume of a series of ionic liquids, and explore the variation of experimentally-measured ε and π* values with molar volume. Both variables are found to vary with molar volume, and we observe an anomaly in the behavior of π* that offers insight on the nanoscale inhomogeneity of ionic liquids. An important outcome of this work is a simple scheme for the estimation of the relative polarities of ionic liquids; while not quantitatively accurate, the scheme permits prediction of the change in solvent polarity on ionic substitution or derivitization. The approach is sufficiently simple that for most commonly-used ionic liquids it can be implemented on a pocket calculator in a matter of minutes, making it a practical aid to researchers seeking to design task-specific ionic liquids." @default.
- W2112462021 created "2016-06-24" @default.
- W2112462021 creator A5001804143 @default.
- W2112462021 date "2008-01-01" @default.
- W2112462021 modified "2023-10-03" @default.
- W2112462021 title "The relationship between solvent polarity and molar volume in room-temperature ionic liquids" @default.
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- W2112462021 doi "https://doi.org/10.1039/b711991g" @default.
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