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- W2112482919 abstract "Base-catalysed condensation of [Co(sen)]3+(1)[sen = 4,4′,4″-ethylidyne-tris(3-azabutan-1-amine)] with formaldehyde yields the stable tri-imine [Co(sim)]3+(2)[sim = 6,6′,6″-ethylidyne-tris(2,5-diazahex-1-ene)] that is converted into the arsenic capped cage molecule [Co(Mearsasar)]3+(3)(Mearsasar = 8-methyl-1,3,6,10,13,16,19-arsahexa-azabicyclo[6.6.6]icosane) by reaction with AsH3; an X-ray crystallographic analysis of (3) reveals an unusual oblique conformation of the encapsulating ligand, which affects the properties of the complex in a marked manner." @default.
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- W2112482919 date "1989-01-01" @default.
- W2112482919 modified "2023-09-25" @default.
- W2112482919 title "Stabilization of an unusual conformation of an encapsulated metal ion cobalt(methylarsasarcophagine): synthesis and structure" @default.
- W2112482919 doi "https://doi.org/10.1039/c39890001648" @default.
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