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- W2112529263 abstract "The nature of the processes of the formation of macromolecules during the thermal treatment of 4-methacryloyloxybenzoic acid (1) and 4-acryloyloxybenzoic acid (6) was studied. It was shown, that during the thermal treatment of 1 at 250°C (above the ceiling temperature of the addition polymerization) only a condensation polymerization (polycondensation) takes place. In the case of 6 both addition and condensation polymerization are possible at these temperatures. The rigid chains of the resulting poly(oxy 1,4 phenylenecarbonyl) (3) are parallelized spontaneously and the corresponding ordered melt exhibits a liquid crystalline state. The rigid chain polymer 3 is formed too as a result of polymeranalogous transformations of the corresponding polymers poly[1-(4-carboxyphenoxycarbonyl)-1-methylethylene] (2) (from 1) and poly[1-(4-carboxyphenoxycarbonyl)ethylene] (7) (from 6)." @default.
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- W2112529263 date "1981-07-01" @default.
- W2112529263 modified "2023-09-27" @default.
- W2112529263 doi "https://doi.org/10.1002/macp.1981.021820702" @default.
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