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- W2112589418 abstract "We present results of the study of transmittance and Raman spectra in BaCl2‐BaO‐TeO2 glasses possessing intense spontaneous Raman scattering which are promising for the development of integrated and fibre stimulated Raman lasers. Compared with oxide‐tellurite systems these glasses are found to be transparent in a wider wavelength range, from 350nm to 6.5 µm. A band near 765cm −1 is found to arise in the Raman spectra of the glasses with total BaO and BaCl2 content exceeding 30mol%. The band turns out to be 70‐80 times as intense as the main Raman band with maximum near 440cm −1 in SiO2 glass. Quantum-chemical calculations of the structure and vibrational spectra of the glasses show that the 765cm −1 band is caused mainly by vibrations of O3Te‐O − and O2Te=O non-bridging oxygen atoms. (Some figures in this article are in colour only in the electronic version)" @default.
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- W2112589418 date "2007-12-19" @default.
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- W2112589418 title "Spectroscopic properties of new BaCl2–BaO–TeO2 tellurite glasses for fibre and integrated optics applications" @default.
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- W2112589418 doi "https://doi.org/10.1088/0022-3727/41/1/015404" @default.
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