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- W2112748891 abstract "(±)-Yellow scale pheromone 1 has been synthesized via the route illustrated in Scheme 1. The [3,3]sigmatropic ring expansion of 8-membered thionocarbonate 4 exclusively produced the (Z)-10-membered thiolcarbonate 3, which was transformed via three steps to the intermediate 2 with all the necessary carbon atoms for the pheromone. Reductive removal of the SCO moiety in 2 followed by acetylation gave 1." @default.
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- W2112748891 date "1993-08-01" @default.
- W2112748891 modified "2023-10-18" @default.
- W2112748891 title "[3,3]Sigmatropic ring expansion of cyclic thionocarbonates. 9. total synthesis of (±)-yellow scale pheromone via 10-membered thiolcarbonate" @default.
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- W2112748891 doi "https://doi.org/10.1016/s0040-4020(01)87241-0" @default.
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