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- W2112789048 abstract "Abstract The coordination chemistry of the organozinc-nitrogen compounds EtZnNPh 2 and EtZnNPhCOZ (ZH, Me, OMe, SMe and NPh 2 ) has been studied. Whereas EtZnNPh 2 is dimeric [as in Zn(NPh 2 ) 2 ], with three-coordinate zinc, replacement of a Ph group in EtZnNPh 2 by COZ leads to higher association and four-coordination of zinc. Such compounds are trimeric in solution with ZOMe and NPH 2 , tetrameric with ZMe, and polymeric ( n > 6) with ZH. The compound with ZSMe decomposes into EtZnSMe and PhNCO above 5°. All compounds readily form four-coordinate complexes with pyridine (Py) and N,N,N′,N′ -tetramethylethylenediamine (TMED). EtZnNPh 2 and EtZnNPhCOZ (ZOMe, SMe, NPh 2 ) yield mononuclear complexes (RZnX·2 Py and RZnX·TMED). The organozinc amides (ZH, Me) yield binuclear complexes [(RZnX·Py) 2 and (RZnX) 2 ·TMED]. Possible structures for these compounds in benzene solution are considered." @default.
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- W2112789048 date "1969-03-01" @default.
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- W2112789048 title "Investigations on organozinc compounds XI. Coordination chemistry of organozinc compounds RZnX: organozinc-nitrogen compounds of the type EtZnNPhCOZ" @default.
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- W2112789048 doi "https://doi.org/10.1016/s0022-328x(00)89760-0" @default.
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