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- W2112941738 endingPage "6529" @default.
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- W2112941738 abstract "A series of 2-dialkylphosphino-2‘-alkoxy-1,1‘-binaphthyl ligands (6a−c and 8a−c) have been prepared conveniently by a lithium-initiated ring-opening reaction of dinaphthofuran, followed by selective phosphorylation. These compounds displayed a remarkable air and moisture stability, both in solid form and in solution. Application of these phosphine ligands in palladium-catalyzed C−N bond forming reactions revealed the crucial roles of the steric bulk of the substituents on the phosphorus atom governing the catalytic activity. Specifically, 2-di-tert-butylphosphino-2‘-isopropoxy-1,1‘-binaphthyl (8b) proved to be the most effective for the aminations of aryl halides with primary amines, while the less bulky 2-dicyclohexyl-2‘-methoxy-1,1‘-binaphthyl (6a) was more effective for the aminations with secondary amines. The steric and electronic effects of the ligands were analyzed to account for these observations." @default.
- W2112941738 created "2016-06-24" @default.
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- W2112941738 date "2006-07-12" @default.
- W2112941738 modified "2023-10-17" @default.
- W2112941738 title "Synthesis of Bulky and Electron-Rich MOP-type Ligands and Their Applications in Palladium-Catalyzed C−N Bond Formation" @default.
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- W2112941738 doi "https://doi.org/10.1021/jo060945k" @default.
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