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- W2112983687 abstract "Abstract 9,10-Phenanthrenequinone (phq) reacts with WCl4(DME) and MoCl4(OEt2)2 to give the complexes tetrachloro[9,10-phenanthrenediolato(2—)-O,O′]tungsten(VI) and tetrachloro[9,10-phenanthrenesemiquinonato(1—)-O,O′]molybdenum(V), respectively; and with the oxohalide complexes MOCl3(DME) (M = Mo, W) to give the complexes trichlorooxo[9,10-phenanthrenequinone-O,O′]molybdenum(V) and trichlorooxo[9,10-phenanthrenesemiquinonato(1—)-O,O′]tungsten(VI). Tetrachloro[3,4,5,6-tetrachloro-1,2-benzenediolato(2—)-O,O′]molybdenum(VI) is obtained in less than 50% yield by reaction of tetrachloro-1,2-benzoquinone (tcq) with MoCl5, and tetrachloro[3,4,5,6-tetrachloro-1,2-benzenediolato(2—)-O,O′]tungsten(VI) is obtained in quantitative yield by reaction of WCl6 with tcq, concomitant with oxidation of the toluene solvent. Tetrachloro[9,10-phenanthrenesemiquinonato(1—)-O,O′]molybdenum(V) reacts with t-BuOSiMe3 to give dichlorooxo[1,1-oxybis(ethane)][9,10-phenanthrenediolato(2—)-O,O′] molybdenum(VI). Based on analytical, IR and magnetic data suggested assignments of formal oxidation states of the metal and the quinone ligands in the complexes are presented." @default.
- W2112983687 created "2016-06-24" @default.
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- W2112983687 date "1993-11-01" @default.
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- W2112983687 title "Preparation of some mixed chloro-catecholate and chloro-oxo-catecholate complexes of high oxidation state tungsten and molybdenum" @default.
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- W2112983687 doi "https://doi.org/10.1016/s0277-5387(00)80083-2" @default.
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