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- W2113010354 abstract "Biomimetic total syntheses of potent antiviral spirooliganones A and B were achieved with 3% and 2% yield, respectively, in 12 steps from commercially available materials. The synthetic strategy was inspired primarily by the biogenetic hypothesis and was enabled by two independent cascade events: (i) an unprecedented reaction involving aromatic Claisen rearrangement/o-quinone methide formation/hetero-Diels-Alder cycloaddition to construct the tetracyclic framework and (ii) phenol oxidative dearomatization/spirocyclization to build the spiro-fused cyclohexadienone/tetrahydrofuran moiety." @default.
- W2113010354 created "2016-06-24" @default.
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- W2113010354 creator A5025184402 @default.
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- W2113010354 date "2014-06-27" @default.
- W2113010354 modified "2023-10-03" @default.
- W2113010354 title "Biomimetic Asymmetric Total Syntheses of Spirooliganones A and B" @default.
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- W2113010354 doi "https://doi.org/10.1021/ol501593m" @default.
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