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- W2113010537 abstract "A new class of linear unsaturated polyphosphate esters based on divanillylidene cyclohexanone possessing liquid crystalline-cum-photocrosslinkable properties have been synthesized from 2,6-bis[n-hydroxyalkyloxy(vanillylidene)]cyclohexanone [n = 6,8,10] with various alkyl/aryl phosphorodichloridates in chloroform at ambient temperature. The resultant polymers were characterized by intrinsic viscosity, FT-IR, 1H, 13C, and 31P-NMR spectroscopy. All the polymers showed anisotropic behavior under hot stage optical polarized microscope (HOPM). The liquid crystalline textures of the polymers became more transparent with increasing spacer length. The thermal behavior of the polymers was studied by thermogravimetric analysis and differential scanning calorimetry. The Tg, Tm, and Ti of the polymers decreased with increasing flexible methylene chain. The photocrosslinking property of the polymer was investigated by UV light/UV spectroscopy; the crosslinking proceeds via 2π-2π cycloaddition reactions of the divanillylidene exocyclic double bond of the polymer backbone. The pendant alkyloxy containing polymers show faster crosslinking than the pendant phenyloxy containing polymers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5215–5226, 2004" @default.
- W2113010537 created "2016-06-24" @default.
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- W2113010537 date "2004-01-01" @default.
- W2113010537 modified "2023-10-16" @default.
- W2113010537 title "Novel thermotropic liquid crystalline-cum-photocrosslinkable polyvanillylidene alkyl/arylphosphate esters" @default.
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- W2113010537 doi "https://doi.org/10.1002/pola.20350" @default.
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