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- W2113013829 abstract "The electrochemical reduction of 2,3′-dinitrobenzidine (I) has been investigated in N,N-dimethylformamide solutions. Three diffusion-controlled polarographic waves were obtained. The first wave is due to a reversible single electron-transfer while the second and third waves result from irreversible processes involving one and two electron-transfers, respectively. The radical anion formed in the first step of reduction was confirmed by ESR technique. The red colour compound formed due to “ion association” after the second electron-transfer step gives rise to a polarographic “minimum” and a “dip” in the chronopotentiogram in addition to the new “peak clusters” seen in cyclic voltammograms. A mechanism is suggested for the reduction of I leading to the formation of 2,3′-dinitrosobenzidine." @default.
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- W2113013829 date "1985-08-01" @default.
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- W2113013829 title "Electrochemical Behaviour of 2,3′-Dinitrobenzidine in N,N-Dimethylformamide" @default.
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- W2113013829 doi "https://doi.org/10.1002/bbpc.19850890814" @default.
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