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• W2113018740 endingPage "14485" @default.
• W2113018740 startingPage "14478" @default.
• W2113018740 abstract "Mixed 3d-4f 12-azametallacrown-4 complexes, [Mn2 Ln2 (OH)2 (hppt)4 (OAc)2 (DMF)2 ]⋅2 DMF⋅H2 O [Ln=Dy (1), Er (2), Yb (3), Tb (4) and Y (5), H2 hppt=3-(2-hydroxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazole)], were synthesized by reactions of H2 hppt with Mn(OAc)2 ⋅4 H2 O and Ln(NO3 )3 ⋅6 H2 O. This is the first 3d-4f azametallacrown family to incorporate Ln ions into the ring sets. These isostructural complexes exhibit alternating arrangements of two Mn and two Ln ions in the rings with each pair of metal centers bound by an NN group and μ2 -O bridging. Magnetic measurements revealed dominant antiferromagnetic interactions between metal centers, and frequency-dependent out-of-phase (${chi {^prime}{^prime}_{rm{M}} }$) signals below 4 K suggest slow relaxation of magnetization." @default.
• W2113018740 created "2016-06-24" @default.
• W2113018740 creator A5003278776 @default.
• W2113018740 creator A5029950470 @default.
• W2113018740 creator A5049010514 @default.
• W2113018740 creator A5067741364 @default.
• W2113018740 creator A5075995463 @default.
• W2113018740 creator A5082252423 @default.
• W2113018740 date "2015-08-21" @default.
• W2113018740 modified "2023-10-12" @default.
• W2113018740 title "A Family of 12-Azametallacrown-4 Structural Motif with Heterometallic Mn^III-Ln-Mn^III-Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single-Molecule Magnet Behavior" @default.
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