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- W2113021314 abstract "The elastic moduli Et of crystal lattices of polymers perpendicular to molecular chain axis are dependent on the intermolecular forces, and can be determined by an X-ray diffraction method. At first, the assumption of “homogeneous stress distribution” used in the evaluation of Et was confirmed experimentally. The Et values of a number of well known polymers were compared and discussed from the viewpoint of intermolecular forces. Hydrogen bonding and dipole forces increased Et, whereas disorders in the crystal lattices and linear side chains decreased Et. As a particular application of Et it can be employed to discriminate whether a comonomer component of a copolymer can enter the crystal lattice or not. Die Elastizitätsmoduln Et der Kristallgitter von Polymeren senkrecht zur Molekülkettenachse hängen von den zwischenmolekularen Kräften ab und können mit Hilfe einer Röntgenstrahlenbeugungs-Methode bestimmt werden. Zuerst wurde die Annahme der «homogenen Spannungsverteilung», die zur Berechnung von Et benützt wurde, experimentell bestätigt. Die Et-Werte einer Anzahl gut bekannter Polymere wurden miteinander verglichen und vom Standpunkt der zwischenmolekularen Kräfte diskutiert. Wasserstoffbrückenbindung und Dipol-Wechselwirkungskräfte erhöhten Et, währen Fehlordnungen im Kristallgitter und lineare Seitenketten Et erniedrigten. Eine spezielle Anwendung des Et-Wertes ist die Unterscheidung, ob eine Comonomer-Komponente eines Copolymeren in das Kristallgitter eingebaut werden kann oder nicht." @default.
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- W2113021314 date "1975-06-01" @default.
- W2113021314 modified "2023-09-26" @default.
- W2113021314 title "Relation between the crystal structure of polymers and the elastic modulus of polymer crystals in the direction perpendicular to the chain axis" @default.
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