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• W2113143114 abstract "The colorless, two-coordinate gold(i) complex, [(H2O)3Na][Au(SCSN3)2], has been synthesized through the [2 + 3] cyclic reaction of carbon disulfide and sodium azide in the presence of the labile complex (tht)AuCl. Metathesis of [(H2O)3Na][Au(SCSN3)2], with tetra(phenyl)arsonium chloride produced colorless needles of (Ph4As)[Au(SCSN3)2]. The structure of [(H2O)3Na][Au(SCSN3)2] involves linear gold coordination by two exocyclic sulfur atoms of the 1,2,3,4-thiatriazole-5-thiolate anions. These two-coordinate anions self-associate to form extended, zig-zag chains that are connected by aurophilic bonding with Au∙∙∙Au distances of 3.2653(3) Å and 3.3090(3) Å. Remarkably, the individual S-Au-S units that are connected though aurophilic interactions are eclipsed. The structure of (Ph4As)[Au(SCSN3)2] also contains linear, two-coordinate gold ions with bonding to the 1,2,3,4-thiatriazole-5-thiolate anionic ligands through the exocyclic sulfur atoms. However, in this salt, the anions self-associate through AuAu bonds (Au∙∙∙Au distance of 3.2007(3) Å) to form simple dimers, which also have an eclipsed arrangement of the ligands. Electronic structure calculations strongly suggest that the staggered geometry for the [(Au(SCSN3))2](+) dimer is energetically favored relative to the eclipsed geometry. However, attractive π-stacking interactions appear to promote the observed eclipsed arrangement of the ligands." @default.
• W2113143114 created "2016-06-24" @default.
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• W2113143114 date "2014-07-29" @default.
• W2113143114 modified "2023-09-26" @default.
• W2113143114 title "Formation and structure of two luminescent salts of [Au(SCSN₃)₂]⁻obtained through the [2 + 3] cyclization of carbon disulfide and azide ion" @default.
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• W2113143114 doi "https://doi.org/10.1039/c4dt01902d" @default.
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