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• W2113163650 startingPage "3668" @default.
• W2113163650 abstract "An efficient synthesis of 11-selena and 11-tellura steroids bearing a pyridine as an A ring was achieved via an intramolecular Diels–Alder cycloaddition of o-quinodimethanes, which were generated from a 3-azabicyclo[4.2.0]octa-1,3,5-trien-7-one ketal. The major isomer matches the trans-anti-trans ring configuration of natural products. Finally, the vinyl groups of the synthesized 11-hetero steroids have been oxidized by the Wacker process in good yields. The characteristic 1H and 13C NMR spectroscopic features of the synthesized compounds are reported." @default.
• W2113163650 created "2016-06-24" @default.
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• W2113163650 date "2011-05-01" @default.
• W2113163650 modified "2023-10-09" @default.
• W2113163650 title "First total syntheses of (±)-3-aza-11-selena and (±)-3-aza-11-tellura steroids" @default.
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• W2113163650 doi "https://doi.org/10.1016/j.tet.2011.03.080" @default.
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