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- W2113165887 abstract "The gas-phase reaction of ozone with vinylcyclohexane and methylene cyclohexane has been investigated at ambient T and p=1 atm of air in the presence of sufficient cyclo-hexane or 2-propanol added to scavenge OH. The reaction rate constants, in units of 10−18 cm3 molecule−1 s−1, are 7.52±0.97 for vinylcyclohexane (T=292±2 K) and 10.6±1.9 for methylene cyclohexane (T=293±2 K). Carbonyl reaction products were cyclohexyl meth-anal (0.62±0.03) and formaldehyde (0.47±0.04) from vinylcyclohexane and cyclohexanone (0.55±0.10) and formaldehyde (0.60±0.05) from methylene cyclohexane, where the yields given in parentheses are expressed as carbonyl formed, ppb/reacted ozone, ppb. The sum of the yields of the primary carbonyls is close to the value of 1.0 that is consistent with the simple mechanisms: O3+cyclo(C6H11)−CH(DOUBLEBOND)CH2→α(HCHO+cyclo(C6H11)CHOO)+(1−α)(HCHOO+cyclo(C6H11)CHO) for vinylcyclohexane and O3+(CH2)5C(DOUBLEBOND)CH2→α(HCHO +(CH2)5COO)+(1−α)(HCHOO+(CH2)5C(DOUBLEBOND)O) for methylene cyclohexane. The coefficients α are 0.43±0.10 for vinylcyclohexane and 0.52±0.05 for methylene cyclohexane, i.e., (formaldehyde+the substituted biradical) and (HCHOO+cyclohexyl methanal or cyclo-hexanone) are formed in ca. equal yields. Reaction rate constants, carbonyl yields, and reaction mechanisms are compared to those for alkene structural homologues. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 855–860, 1997" @default.
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- W2113165887 date "1997-01-01" @default.
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- W2113165887 title "A kinetic and product study of the gas-phase reaction of ozone with vinylcyclohexane and methylene cyclohexane" @default.
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- W2113165887 doi "https://doi.org/10.1002/(sici)1097-4601(1997)29:11<855::aid-kin7>3.0.co;2-l" @default.
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