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- W2113173362 abstract "Abstract A new route to the diarylheptanoid diospongins A and B was developed. The key step is a novel, one‐pot, sequential dirhodium(II) tetrakis[( S )‐3‐(benzo‐fused phthalimido)‐2‐piperidinonate] [Rh 2 ( S ‐BPTPI) 4 ] catalyzed enantioselective hetero‐Diels–Alder/TMSOTf‐catalyzed Mukaiyama–Michael reaction process. The sign of the optical rotation of natural diospongin B was determined to be (+) and not (–) as was originally reported." @default.
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- W2113173362 date "2010-10-27" @default.
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- W2113173362 title "A Short, Catalytic, Asymmetric Synthesis of Diospongins A and B by a One‐Pot, Sequential Hetero‐Diels–Alder/Mukaiyama–Michael Reaction Process" @default.
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- W2113173362 doi "https://doi.org/10.1002/ejoc.201001125" @default.
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