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• W2113176844 abstract "One-at-a-time stereochemistry: AsS bond-making and bond-breaking reactions are important in pharmacology, toxicology, and cell biology. The aqueous covalent chemistry of individual AsIII molecules can be monitored inside a protein nanoreactor. The approach is used to follow the creation of a chiral center at AsIII, through the formation of a short-lived AsS bond, and to monitor inversion at that center (see picture). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z700736_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2113176844 date "2007-09-20" @default.
• W2113176844 modified "2023-10-18" @default.
• W2113176844 title "Formation of a Chiral Center and Pyrimidal Inversion at the Single-Molecule Level" @default.
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• W2113176844 doi "https://doi.org/10.1002/anie.200700736" @default.
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