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• W2113186669 startingPage "776" @default.
• W2113186669 abstract "Polymethylmethacrylate (PMMA)/ceria composite fibres were synthesized by using a sequential combination of polymer electrospinning, spray-coating with a sol, and a final calcination step to yield microstructured ceria tubes, which are composed of nanocrystalline ceria particles. The PMMA template is removed from the organic/inorganic hybrid material by radio frequency (rf) plasma etching followed by calcination of the ceramic green-body fibres. Microsized ceria (CeO(2)) tubes, with a diameter of ca. 0.75 µm, composed of nanocrystalline agglomerated ceria particles were thus obtained. The 1-D ceramic ceria material was characterized by X-ray diffraction, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), UV-vis and photoluminescence spectroscopy (PL), as well as thermogravimetric analysis (TGA). Its catalytic performance was studied in the direct carboxylation of methanol with carbon dioxide leading to dimethyl carbonate [(CH(3)O)(2)CO, DMC], which is widely employed as a phosgene and dimethyl sulfate substitute, and as well as a fuel additive." @default.
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• W2113186669 date "2011-11-30" @default.
• W2113186669 modified "2023-10-01" @default.
• W2113186669 title "Template-assisted formation of microsized nanocrystalline CeO₂ tubes and their catalytic performance in the carboxylation of methanol" @default.
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• W2113186669 doi "https://doi.org/10.3762/bjnano.2.86" @default.
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