FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2113196618> ?p ?o ?g. }

• W2113196618 endingPage "1700" @default.
• W2113196618 startingPage "1687" @default.
• W2113196618 abstract "Abstract The reduction of [Mo 2 (Cp) 2 (µ‐SMe) 3 (µ‐O)] + ( 1 + ) has been investigated by cyclic voltammetry and controlled‐potential electrolysis in THF‐ and MeCN/NBu 4 PF 6 without added acid or in the presence of various acids HX (HX: HTsO, CF 3 CO 2 H, HBF 4 ). Reduction in the presence of acid follows an EC rev E mechanism in which the intermediate chemical step is an acid‐base equilibrium between 1 and [Mo 2 (Cp) 2 (µ‐SMe) 3 (µ‐OH)] + ( 2 + ). This electrochemical process is followed by protonation of the neutral µ‐hydroxo complex 2 to afford different products which depend both on the solvent (THF or MeCN) and on the nature of the acid. Controlled‐potential electrolysis of 1 + in the presence of HX (2 equiv.) leads to the generation of binding sites and finally gives products identical to those obtained from protonation of 2 by HX. The complex [Mo 2 (Cp) 2 (µ‐SMe) 3 (µ‐η 1 ,η 1 ‐OCOCF 3 )] ( 3 ) which can be obtained either by protonation of 2 by CF 3 CO 2 H or by reduction of 1 + in the presence of CF 3 CO 2 H, has been characterized crystallographically. In the presence of HBF 4 protonation of 1 + gives 2 2+ . The reactivity of 2 + and of the complexes [Mo 2 (Cp) 2 (µ‐SMe) 3 (H 2 O)(TsO)] ( 4 ) and [Mo 2 (cp) 2 (µ‐SMe) 3 (H 2 O)L] + (L = H 2 O or THF) ( 6 + ), all of which contain a terminal aqua ligand, has also been investigated. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
• W2113196618 created "2016-06-24" @default.
• W2113196618 creator A5001865773 @default.
• W2113196618 creator A5058468705 @default.
• W2113196618 creator A5061799367 @default.
• W2113196618 creator A5068579932 @default.
• W2113196618 creator A5072588314 @default.
• W2113196618 creator A5083781756 @default.
• W2113196618 date "2004-04-01" @default.
• W2113196618 modified "2023-10-17" @default.
• W2113196618 title "Electrochemical Studies of Complexes with Oxo‐ or Hydroxo‐Bridged {Mo₂(µ‐SMe)₃}⁺ Centers: Cleavage of the Oxygen Bridge and Generation of Substrate‐Binding Sites" @default.
• W2113196618 cites W1965055554 @default.
• W2113196618 cites W1977259364 @default.
• W2113196618 cites W1979495363 @default.
• W2113196618 cites W1992984456 @default.
• W2113196618 cites W2000800848 @default.
• W2113196618 cites W2004081825 @default.
• W2113196618 cites W2016626713 @default.
• W2113196618 cites W2019291629 @default.
• W2113196618 cites W2021627036 @default.
• W2113196618 cites W2025218085 @default.
• W2113196618 cites W2034439593 @default.
• W2113196618 cites W2038077864 @default.
• W2113196618 cites W2044588335 @default.
• W2113196618 cites W2052940336 @default.
• W2113196618 cites W2057581700 @default.
• W2113196618 cites W2062362336 @default.
• W2113196618 cites W2063334178 @default.
• W2113196618 cites W2066623747 @default.
• W2113196618 cites W2066815433 @default.
• W2113196618 cites W2070096772 @default.
• W2113196618 cites W2072565024 @default.
• W2113196618 cites W2075806292 @default.
• W2113196618 cites W2077209339 @default.
• W2113196618 cites W2081384736 @default.
• W2113196618 cites W2085588392 @default.
• W2113196618 cites W2096756081 @default.
• W2113196618 cites W2109888724 @default.
• W2113196618 cites W2117614133 @default.
• W2113196618 cites W2129014756 @default.
• W2113196618 cites W2162689516 @default.
• W2113196618 cites W2949183818 @default.
• W2113196618 cites W3138501055 @default.
• W2113196618 doi "https://doi.org/10.1002/ejic.200300707" @default.
• W2113196618 hasPublicationYear "2004" @default.
• W2113196618 type Work @default.
• W2113196618 sameAs 2113196618 @default.
• W2113196618 citedByCount "9" @default.
• W2113196618 countsByYear W21131966182014 @default.
• W2113196618 countsByYear W21131966182017 @default.
• W2113196618 crossrefType "journal-article" @default.
• W2113196618 hasAuthorship W2113196618A5001865773 @default.
• W2113196618 hasAuthorship W2113196618A5058468705 @default.
• W2113196618 hasAuthorship W2113196618A5061799367 @default.
• W2113196618 hasAuthorship W2113196618A5068579932 @default.
• W2113196618 hasAuthorship W2113196618A5072588314 @default.
• W2113196618 hasAuthorship W2113196618A5083781756 @default.
• W2113196618 hasConcept C111368507 @default.
• W2113196618 hasConcept C116569031 @default.
• W2113196618 hasConcept C127313418 @default.
• W2113196618 hasConcept C142724271 @default.
• W2113196618 hasConcept C145148216 @default.
• W2113196618 hasConcept C147789679 @default.
• W2113196618 hasConcept C155647269 @default.
• W2113196618 hasConcept C163127949 @default.
• W2113196618 hasConcept C170493617 @default.
• W2113196618 hasConcept C17525397 @default.
• W2113196618 hasConcept C178790620 @default.
• W2113196618 hasConcept C179104552 @default.
• W2113196618 hasConcept C185592680 @default.
• W2113196618 hasConcept C204787440 @default.
• W2113196618 hasConcept C2776910235 @default.
• W2113196618 hasConcept C2777289219 @default.
• W2113196618 hasConcept C2777869211 @default.
• W2113196618 hasConcept C2778288590 @default.
• W2113196618 hasConcept C2780471494 @default.
• W2113196618 hasConcept C30095370 @default.
• W2113196618 hasConcept C52859227 @default.
• W2113196618 hasConcept C55493867 @default.
• W2113196618 hasConcept C68801617 @default.
• W2113196618 hasConcept C71240020 @default.
• W2113196618 hasConcept C71924100 @default.
• W2113196618 hasConcept C8010536 @default.
• W2113196618 hasConceptScore W2113196618C111368507 @default.
• W2113196618 hasConceptScore W2113196618C116569031 @default.
• W2113196618 hasConceptScore W2113196618C127313418 @default.
• W2113196618 hasConceptScore W2113196618C142724271 @default.
• W2113196618 hasConceptScore W2113196618C145148216 @default.
• W2113196618 hasConceptScore W2113196618C147789679 @default.
• W2113196618 hasConceptScore W2113196618C155647269 @default.
• W2113196618 hasConceptScore W2113196618C163127949 @default.
• W2113196618 hasConceptScore W2113196618C170493617 @default.
• W2113196618 hasConceptScore W2113196618C17525397 @default.
• W2113196618 hasConceptScore W2113196618C178790620 @default.
• W2113196618 hasConceptScore W2113196618C179104552 @default.
• W2113196618 hasConceptScore W2113196618C185592680 @default.
• W2113196618 hasConceptScore W2113196618C204787440 @default.
• W2113196618 hasConceptScore W2113196618C2776910235 @default.

• next