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- W2113244504 abstract "We investigated the photoelectrochemical behavior of type 304 stainless steel (SUS 304) with TiO 2 thin film coatings, applied by a spray pyrolysis technique, for the purpose of cathodic photoprotection of the steel from corrosion. The photopotential of TiO 2 -coated SUS 304 was -350 mV vs. Ag/AgCl in an aerated aqueous solution containing 3 wt NaCl (pH 7) under illumination with 10 mW cm -2 ultraviolet (UV) light, which was more negative than the corrosion potential of the bare steel (-100 mV). The photopotential did not change in aqueous solutions containing from 0.01 to 5 wt % NaCl. No corrosion of TiO 2 -coated steel was observed at pH values greater than 3 in 3 wt % NaCl aqueous solution under UV illumination. TiO 2 films with coverages greater than 30% achieved photoprotection ability at pH 6. When the UV light intensity was 3 mW cm -2 , that is, comparable with a typical daylight UV intensity in Tokyo the photopotential of TiO 2 -coated SUS 304 was -220 mV in an aerated 3 wt % NaCl aqueous solution. In addition, the bleaching of methylene blue dye was confirmed on TiO 2 -coated SUS 304 under 1 mW cm -2 UV illumination. We conclude that TiO 2 thin film-coated SUS 304 exhibits both a cathodic photoprotection effect against corrosion and the previously reported photocatalytic self-cleaning effect." @default.
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- W2113244504 date "2001-01-01" @default.
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- W2113244504 title "Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO[sub 2] Coating for Type 304 Stainless Steel" @default.
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- W2113244504 doi "https://doi.org/10.1149/1.1339030" @default.
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