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• W2113256961 endingPage "4401" @default.
• W2113256961 startingPage "4396" @default.
• W2113256961 abstract "A systematic study was carried out to explore the electrochemical behaviour of Ce in an EMIES ionic liquid at a glassy carbon (GC) electrode over the range 298–351 K. The electrode reaction of CeIII/CeIV was found to be quasi-reversible by cyclic voltammetry. An increase in the current intensity was obtained with an increase in temperature. The diffusion coefficients (Do), the transfer coefficients (α) of CeIII and the charge-transfer rate constants (ks) were estimated. The apparent standard potential (E0*) and the thermodynamic properties of the oxidation of CeIII to CeIV were also investigated. A photoluminescence investigation on cerium extracted in EMIES ionic liquid shows the stabilization of cerium in the CeIII state. There is a broad band at 350 nm, which is attributed to the 5d1→4f1 transitions. With an increase in temperature the CeIII peak intensity decreases gradually and is almost flattened at 350 K. This may be a result of CeIII being converted into CeIV with an increase in temperature and then not being luminescence-active as it is an f0 system." @default.
• W2113256961 created "2016-06-24" @default.
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• W2113256961 date "2015-08-17" @default.
• W2113256961 modified "2023-10-18" @default.
• W2113256961 title "Electrochemical, Thermodynamic and Spectroscopic Investigations of Ce ^III in a 1‐Ethyl‐3‐methylimidazolium Ethyl Sulfate (EMIES) Ionic Liquid" @default.
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• W2113256961 doi "https://doi.org/10.1002/ejic.201500671" @default.
• W2113256961 hasPublicationYear "2015" @default.
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