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- W2113273359 endingPage "10077" @default.
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- W2113273359 abstract "Donor–acceptor trumps: The chlorosilyliumylidene salt 2 with a three-coordinate silicon(II) atom is accessible through ligand exchange between NHCSiCl2 and the electron-rich bis(ylide) ligand 1. The cation in 2 represents a donor-stabilized form of the elusive [ClSi:] cation and could be fully characterized, including X-ray diffraction analysis. Oxidation of 2 with elemental sulfur furnished 3 as the sole product." @default.
- W2113273359 created "2016-06-24" @default.
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- W2113273359 date "2012-09-10" @default.
- W2113273359 modified "2023-10-18" @default.
- W2113273359 title "The Elusive Silyliumylidene [ClSi:]<sup>+</sup>and Silathionium [ClSiS]<sup>+</sup>Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand" @default.
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- W2113273359 doi "https://doi.org/10.1002/anie.201205840" @default.
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