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• W2113276872 endingPage "2837" @default.
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• W2113276872 abstract "Abstract A novel multiblock aromatic–aliphatic copolyester poly(ethylene‐ co ‐1,6‐hexene terephthalate)‐copoly(1,4‐dioxan‐2‐one) (PEHT‐PPDO) was successfully synthesized via the chain‐extension reaction of dihydroxyl teminated poly(ethylene‐ co ‐hexane terephthalate) (PEHT‐OH) with dihydroxyl teminated poly(1,4‐dioxan‐2‐one) (PPDO‐OH) prepolymers, using toluene‐2,4‐diisocyanate as a chain extender. To produce PEHT‐OH prepolymer with an appropriate melting point which can match the reaction temperature of PEHT‐OH prepolymer with PPDO‐OH prepolymer, 1,6‐hexanediol was used to disturb the regularity of poly(ethylene terephthalate) segments. The chemical structures and molecular weights of PEHT‐PPDO copolymers were characterized by 1 H NMR, FTIR, and GPC. The DSC data showed that PPDO‐OH segments were miscible well with PEHT‐OH segments in amorphous state and that the crystallization of copolyester was predominantly contributed by PPDO segments. The TGA results indicated that the thermal stability of PEHT‐PPDO was improved comparing with PPDO homopolymer. The novel aromatic–aliphatic copolyesters have good mechanical properties and could find applications in the field of biodegradable polymer materials. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2828–2837, 2010" @default.
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• W2113276872 date "2010-05-24" @default.
• W2113276872 modified "2023-10-18" @default.
• W2113276872 title "A novel aromatic-aliphatic copolyester consisting of poly(1,4-dioxan-2-one) and poly(ethylene-co-1,6-hexene terephthalate): Preparation, thermal, and mechanical properties" @default.
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• W2113276872 doi "https://doi.org/10.1002/pola.24056" @default.
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