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• W2113284470 abstract "The 2-picolinium N-ylide 4, generated in situ from the N-acylmethyl-2-picolinium bromide 3, underwent cycloaddition to N-phenylmaleimide or carbon disulfide to give the corresponding cycloadducts 6 and 8, respectively similar reactions of compound 3 with some electron-deficient alkenes in the presence of MnO(2) yielded the products 11 and 12. In addition, reaction of 4 with arylidene cyanothioacetamide andmalononitrile derivatives afforded the thiophene and aniline derivatives 15 and 17, respectively. Heating of picolinium bromide 3 with triethylamine in benzene furnished 2-(2-thienyl)indolizine (18). The structures of the isolated products were confirmed by elemental analysis as well as by (1)H- and (13)C-NMR, IR, and MS data. Both the stereochemistry and the regioselectivity of the studied reactions are discussed. The biological activity of the newly synthesized compounds was examined and showed promising results." @default.
• W2113284470 created "2016-06-24" @default.
• W2113284470 creator A5029269381 @default.
• W2113284470 date "2008-05-01" @default.
• W2113284470 modified "2023-10-08" @default.
• W2113284470 title "Facile Synthesis of Heterocycles via 2-Picolinium Bromide and Antimicrobial Activities of the Products" @default.
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• W2113284470 doi "https://doi.org/10.3390/molecules13051066" @default.
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