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- W2113309279 abstract "Raman spectra of oriented β-NaN3 single crystals were taken in b(cc)a, b(cb)a, a(bb)c and a(ba)c orientations. Because of the simple structure R3m (Z = 1), the observed intensities can be interpreted on the basis of an oriented gas model. A new assignment is given for the weak bands: 1278 cm−1 (Eg of 2ν2), 1269 cm−1 (A1g of 2ν2), 1260 cm−1 (A1g of 030←010), 1368 cm−1 (110←010). Electro-optical parameters and first-order bond moments are calculated for the NN bonds: a∥=3.47 Å2, α′⊥=1.33 Å2, μ=0.57 D, dμ/dr=8.34 D Å−1." @default.
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- W2113309279 date "1984-12-01" @default.
- W2113309279 modified "2023-10-14" @default.
- W2113309279 title "Raman intensities and electro-optical parameters of the azide ion in β-NaN3 single crystals and aqueous solution" @default.
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- W2113309279 doi "https://doi.org/10.1002/jrs.1250150612" @default.
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