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• W2113309304 abstract "Abstract Treatment of the polyfunctional ylide Ph 3 P=C(H)C(O)CH 2 COOEt ( 1 ) with the solvated complexes [M(C ∧ X)(THF) 2 ]ClO 4 gave the O , O′ derivatives [M(C ∧ X)(Ph 3 PCH 2 C( O )=C(H)−C(= O )OEt‐κ‐ O , O′ ]ClO 4 [M(C ∧ X) = Pd(C 6 H 4 CH 2 NMe 2 ) ( 2 ), Pd(CH 2 C 9 H 6 N) ( 3 ), Pd(NC 5 H 4 ‐2‐C 6 H 4 ) ( 4 ), Pd(NC 13 H 8 ) ( 5 ), Pd[( S )−C 6 H 4 C(H)MeNMe 2 ] ( 6 ), Pt[ o‐ CH 2 C 6 H 4 P( o‐ tol) 2 ] ( 7 ), Pd[ o‐ CH 2 C 6 H 4 P( o‐ tol) 2 ] ( 8 ), and Pd(C 6 F 5 )(SC 4 H 8 ) ( 9 )]. During the reaction, one proton of the methylene unit is transferred to the ylidic carbon, which is transformed into a phosphonium group generating the zwitterion [Ph 3 PCH 2 C( O )=C(H)−C(= O )OEt], which coordinates to the metal center as an O , O ′‐chelating ligand. Treatment of 1 with [AuCl(SC 4 H 8 )] or [Au(PPh 3 )(OCMe 2 )]ClO 4 gave [AuCl{C(H)(PPh 3 )C(O)CH 2 COOEt}] ( 10 ) or [Au{C(H)(PPh 3 )C(O)CH 2 COOEt}(PPh 3 )]ClO 4 ( 11 ), in which the ylide is C ‐bonded. The X‐ray crystal structures of complexes 2a , 9 and 10 have been determined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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• W2113309304 date "2004-05-25" @default.
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• W2113309304 title "Different Coordination Modes of the Polyfunctional Ylide Ph ₃ P=C(H)C(O)CH ₂ C(O)OEt: <i>C‐</i> vs. <i>O</i> , <i>O′</i> ‐Bonding in Pd ^II , Pt ^II and Au ^I Complexes" @default.
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• W2113309304 doi "https://doi.org/10.1002/ejic.200300801" @default.
• W2113309304 hasPublicationYear "2004" @default.
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