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- W2113309739 abstract "In this work, we report the self-assembly in heptane of ω-dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprenes into micellar aggregates and the use of these nano-objects to support alkylated metallocenes toward ethylene polymerization. Dynamic light scattering was used to demonstrate the self-assembly and the formation of the micellar structures having a core of polar dimethyl ammonium tetrakis-pentafluorophenyl borate moieties, and a corona of polyisoprene (PI). The latter were then used as organic supports for alkylated metallocenes to produce unprecedented millimetric polyethylene beads without loss of catalytic activity." @default.
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- W2113309739 date "2012-01-01" @default.
- W2113309739 modified "2023-09-27" @default.
- W2113309739 title "ω-Dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprene as an organic template for alkylated metallocenes toward the synthesis of polyethylene beads" @default.
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- W2113309739 doi "https://doi.org/10.1039/c2py00588c" @default.
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