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- W2113325458 abstract "The results of research on exoelectron emission (EEE) from the surfaces of three various materials (pure SnO 2 , Sn-Ce-Rh-O, and SnO 2 + RuO 2 + Pt) applied both to sensor technology, i.e., to resistive gas sensors, and to heterogeneous catalysis is presented. The materials reveal different properties in both fields. The studied materials were produced on the basis of tin dioxide, which is the major gas-sensitive component of high sensitivity and low selectivity. Pure SnO 2 , as a catalyst in primary alcohol condensation to ketone, is characterized by a high level of conversion but low selectivity, and consequently, a comparable yield of such products as aldehyde, ketone, or ester. The two-phase composition Sn-Ru-O-Pt applied as oxide catalyst to the studied condensation is characterized by the highest activity at low temperatures among the studied materials and low selectivity. Composition Sn-Ce-Rh-O, contrary to the previous materials. shows the so-called anomalous response of gas sensors, in, i.e., the presence of reductive gases its resistance increases rather than decreases, while in the studied reaction, as a heterogeneous catalyst, clearly high selectivity and yield of ketone results. EEE measurements allow us to suppose that the qualitative measure of the oxygen molecule adsorption is the rate of EEE decay from the surfaces of the materials." @default.
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- W2113325458 date "2003-01-01" @default.
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- W2113325458 title "Exoelectron Emission from Tin Oxide Materials" @default.
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