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- W2113380444 abstract "The x values and electrical conductivity of the nonstoichiometric compound NbO have been measured in a temperature range 700 to 1100 under oxygen partial pressure of 2 10 ∼ 1 10 atm. The NbO is a stoichiometrical compound of NbO under oxygen partial pressure higher than 1.0 10 atm at the above temperature range. The x values were found to vary between 2.48491 and 2.49900 in a temperature range 700 to 1100 under oxygen partial pressure lower than 1 10 atm. The enthalpy of the formation for x' in NbO() increased of 15.98 to 17.26 kcal/mol under the conditions. The electrical conductivity () of the oxide varied from 10 to 10 ohmcm in the above conditions. The activation energy for the conduction was about 1.7 eV. The oxygen pressure dependency of the conductivity (or 1/n value) was about -1/4. The nonstoichiometric conduction mechanism of the oxide has been discussed with the x' values, the values, and the thermodynamic data." @default.
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- W2113380444 date "1991-01-01" @default.
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- W2113380444 title "Nonstoichiometry of the Niobium Oxide" @default.
- W2113380444 hasPublicationYear "1991" @default.
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