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- W2113403249 endingPage "2092" @default.
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- W2113403249 abstract "Abstract Five novel conjugated copolymers ( P1 – P5 ) containing coplanar cyclopentadithiophene (CPDT) units (incorporated with arylcyanovinyl and keto groups in different molar ratios) were synthesized and developed for the applications of polymer solar cells (PSCs). Polymers P1 – P5 covered broad absorption ranges from UV to near infrared (400–900 nm) with narrow optical band gaps of 1.38–1.70 eV, which are compatible with the maximum solar photon reflux. Partially reversible p ‐ and n ‐doping processes of P1 – P5 in electrochemical experiments were observed, and the proper molecular design for highest occupied molecular orbital (HOMO)/lowest unoccupied molecular orbital (LUMO) levels of P1 – P5 induced the highest photovoltaic open‐circuit voltage in the PSC devices, compared with those previously reported CPDT‐based narrow‐band‐gap polymers. Powder X‐ray diffraction (XRD) analyses suggested that these copolymers formed self‐assembled π‐π stacking and pseudobilayered structures. Under 100 mW/cm 2 of AM 1.5 white‐light illumination, bulk heterojunction PSC devices containing an active layer of electron donor polymers P1 – P5 mixed with electron acceptor [6,6]‐phenyl C 61 butyric acid methyl ester (PCBM) in the weight ratio of 1:4 were investigated. The PSC device containing P1 gave the best preliminary result with an open‐circuit voltage of 0.84 V, a short‐circuit current of 2.36 mA/cm 2 , and a fill factor of 0.38, offering an overall power conversion efficiency (PCE) of 0.77% as well as a maximal quantum efficiency of 23% from the external quantum efficiency (EQE) measurements. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2073–2092, 2009" @default.
- W2113403249 created "2016-06-24" @default.
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- W2113403249 date "2009-03-11" @default.
- W2113403249 modified "2023-10-18" @default.
- W2113403249 title "Soluble narrow-band-gap copolymers containing novel cyclopentadithiophene units for organic photovoltaic cell applications" @default.
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- W2113403249 doi "https://doi.org/10.1002/pola.23312" @default.
- W2113403249 hasPublicationYear "2009" @default.
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