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- W2113404549 abstract "The temperature-dependent luminescence of Sm2+ ions in MBPO5 (M=Ca2+,Sr2+,Ba2+) was studied. At low temperature, Sm2+ in this series shows 4f6→4f6 luminescence with only a single emission line observed for the 5D0→7F0 transition, revealing that only one crystallographic cationic site is available for Sm2+ in all the hosts. With increasing temperature, the emission intensity of the 5D0→7F0 transition increases whereas that of the 5D0→7F1 transitions decreases. The 5D1→7F0 transitions of Sm2+ were observed in BaBPO5 and its intensity increases with increasing temperature. At 450K, a broad band of the 4f55d→4f6 luminescent transition of Sm2+ in SrBPO5 and BaBPO5 with maximum at ∼600nm appears due to the thermal population. The lifetime of the 5D0→7F0 transition was recorded at different temperatures, showing a single exponential decay for Sm2+ in SrBPO5 and BaBPO5 but a non-single-exponential decay in CaBPO5." @default.
- W2113404549 created "2016-06-24" @default.
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- W2113404549 date "2003-03-01" @default.
- W2113404549 modified "2023-09-25" @default.
- W2113404549 title "The luminescence of Sm2+ in alkaline earth borophosphates" @default.
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- W2113404549 doi "https://doi.org/10.1016/s0022-2313(02)00410-6" @default.
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