FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2113458732> ?p ?o ?g. }

• W2113458732 endingPage "2788" @default.
• W2113458732 startingPage "2781" @default.
• W2113458732 abstract "The preparation, single crystal and molecular structures of the compounds (BDI)Mg(OCMe2COOEt)(L) are described where BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene and L = pyridine (py) and 4-dimethylaminopyridine (DMAP). In the solid-state the molecules have five coordinate Mg(2+) ions that may be considered as derived from a trigonal bipyramid where the chelating BDI and OCMe2COOEt ligands span equatorial-axial sites. IR spectroscopic data obtained in CH2Cl2 indicate that the chelating nature of the OCMe2COOEt ligand is maintained in solution and variable temperature NMR studies reveal that the ligands py or DMAP undergo a rapid reversible dissociation in toluene-d8 and especially in THF-d8. This leads to a facile exchange involving coordinated and free L upon the addition of L and evidence is presented to support the view that this occurs exclusively by a dissociative interchange mechanism. Zinc forms a related complex (BDI)Zn(OCMe2COOEt) lacking additional coordination of L but maintaining the chelating nature of the OCMe2COOEt ligand and undergoing reversible coordination of L in the presence of added ligands L. The magnesium and zinc complexes will initiate and sustain the living polymerization of lactide (L- or rac-LA) but not the ring-opening polymerization of ε-caprolactone." @default.
• W2113458732 created "2016-06-24" @default.
• W2113458732 creator A5004096016 @default.
• W2113458732 creator A5029511049 @default.
• W2113458732 creator A5044829217 @default.
• W2113458732 creator A5045541286 @default.
• W2113458732 date "2014-01-01" @default.
• W2113458732 modified "2023-10-18" @default.
• W2113458732 title "Ethyl 2-hydroxy-2-methylpropanoate derivatives of magnesium and zinc. The effect of chelation on the homo- and copolymerization of lactide and ε-caprolactone" @default.
• W2113458732 cites W1967984957 @default.
• W2113458732 cites W1970042012 @default.
• W2113458732 cites W1970746106 @default.
• W2113458732 cites W1978815693 @default.
• W2113458732 cites W1990758393 @default.
• W2113458732 cites W2003953360 @default.
• W2113458732 cites W2007613643 @default.
• W2113458732 cites W2008950486 @default.
• W2113458732 cites W2015088677 @default.
• W2113458732 cites W2015784993 @default.
• W2113458732 cites W2021795513 @default.
• W2113458732 cites W2024266054 @default.
• W2113458732 cites W2025253375 @default.
• W2113458732 cites W2025565920 @default.
• W2113458732 cites W2029255146 @default.
• W2113458732 cites W2036620431 @default.
• W2113458732 cites W2043630753 @default.
• W2113458732 cites W2053119414 @default.
• W2113458732 cites W2059375945 @default.
• W2113458732 cites W2063334178 @default.
• W2113458732 cites W2072199055 @default.
• W2113458732 cites W2077823112 @default.
• W2113458732 cites W2079939694 @default.
• W2113458732 cites W2082264584 @default.
• W2113458732 cites W2092337099 @default.
• W2113458732 cites W2095609090 @default.
• W2113458732 cites W2105249240 @default.
• W2113458732 cites W2111115122 @default.
• W2113458732 cites W2131350133 @default.
• W2113458732 cites W2161709073 @default.
• W2113458732 cites W2323645451 @default.
• W2113458732 cites W4232347877 @default.
• W2113458732 doi "https://doi.org/10.1039/c3dt52553h" @default.
• W2113458732 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24201652" @default.
• W2113458732 hasPublicationYear "2014" @default.
• W2113458732 type Work @default.
• W2113458732 sameAs 2113458732 @default.
• W2113458732 citedByCount "31" @default.
• W2113458732 countsByYear W21134587322014 @default.
• W2113458732 countsByYear W21134587322015 @default.
• W2113458732 countsByYear W21134587322016 @default.
• W2113458732 countsByYear W21134587322017 @default.
• W2113458732 countsByYear W21134587322018 @default.
• W2113458732 countsByYear W21134587322020 @default.
• W2113458732 countsByYear W21134587322021 @default.
• W2113458732 countsByYear W21134587322022 @default.
• W2113458732 crossrefType "journal-article" @default.
• W2113458732 hasAuthorship W2113458732A5004096016 @default.
• W2113458732 hasAuthorship W2113458732A5029511049 @default.
• W2113458732 hasAuthorship W2113458732A5044829217 @default.
• W2113458732 hasAuthorship W2113458732A5045541286 @default.
• W2113458732 hasConcept C102931765 @default.
• W2113458732 hasConcept C111592845 @default.
• W2113458732 hasConcept C115624301 @default.
• W2113458732 hasConcept C116569031 @default.
• W2113458732 hasConcept C155647269 @default.
• W2113458732 hasConcept C170493617 @default.
• W2113458732 hasConcept C178516000 @default.
• W2113458732 hasConcept C178790620 @default.
• W2113458732 hasConcept C179104552 @default.
• W2113458732 hasConcept C185592680 @default.
• W2113458732 hasConcept C188027245 @default.
• W2113458732 hasConcept C197404232 @default.
• W2113458732 hasConcept C2776743539 @default.
• W2113458732 hasConcept C2779485729 @default.
• W2113458732 hasConcept C32909587 @default.
• W2113458732 hasConcept C44228677 @default.
• W2113458732 hasConcept C521977710 @default.
• W2113458732 hasConcept C535196362 @default.
• W2113458732 hasConcept C543218039 @default.
• W2113458732 hasConcept C55493867 @default.
• W2113458732 hasConcept C71240020 @default.
• W2113458732 hasConceptScore W2113458732C102931765 @default.
• W2113458732 hasConceptScore W2113458732C111592845 @default.
• W2113458732 hasConceptScore W2113458732C115624301 @default.
• W2113458732 hasConceptScore W2113458732C116569031 @default.
• W2113458732 hasConceptScore W2113458732C155647269 @default.
• W2113458732 hasConceptScore W2113458732C170493617 @default.
• W2113458732 hasConceptScore W2113458732C178516000 @default.
• W2113458732 hasConceptScore W2113458732C178790620 @default.
• W2113458732 hasConceptScore W2113458732C179104552 @default.
• W2113458732 hasConceptScore W2113458732C185592680 @default.
• W2113458732 hasConceptScore W2113458732C188027245 @default.
• W2113458732 hasConceptScore W2113458732C197404232 @default.
• W2113458732 hasConceptScore W2113458732C2776743539 @default.
• W2113458732 hasConceptScore W2113458732C2779485729 @default.
• W2113458732 hasConceptScore W2113458732C32909587 @default.
• W2113458732 hasConceptScore W2113458732C44228677 @default.
• W2113458732 hasConceptScore W2113458732C521977710 @default.

• next