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- W2113517375 abstract "Abstract From the two nitrogen‐rich ligands BT 2− (BT=5,5′‐bitetrazole) and BTT 3− (BTT=1,3‐bis(1 H ‐tetrazol‐5‐yl)triazene), a series of novel rare earth metal complexes were synthesised. For the BT ligand, a vast number of these complexes could be structurally characterised by single‐crystal XRD, revealing structures ranging from discrete molecular aggregates to salt‐like compounds. The isomorphous complexes [La 2 (BT) 3 ] ⋅ 14 H 2 O ( 1 ) and [Ce 2 (BT) 3 ] ⋅ 14 H 2 O ( 2 ) reveal discrete molecules in which one BT 2− acts as a bridging ligand and two BT groups as chelating ligands. The complexes, [M(BT)(H 2 O) 7 ] 2 [BT] ⋅ x H 2 O ( 3 – 5 ), (M=Nd ( 3 ), Sm ( 4 ), and Eu ( 5 )), are also isomorphous and consist of [M(BT)(H 2 O) 7 ] + ions in which only one BT 2− acts as a chelate ligand for each metal centre. [Tb(H 2 O) 8 ] 2 [BT] 3 ⋅ x H 2 O ( 6 ) and [Er(H 2 O) 8 ] 2 [BT] 3 ⋅ x H 2 O ( 7 ) are salt‐like compounds that do not exhibit any significant metal–nitrogen contacts. In the BTT–samarium compound 9 , discrete molecules were found in which BTT 3− acts as a tridentate ligand with three SmN bonds." @default.
- W2113517375 created "2016-06-24" @default.
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- W2113517375 date "2008-04-09" @default.
- W2113517375 modified "2023-10-17" @default.
- W2113517375 title "New Rare Earth Metal Complexes with Nitrogen-Rich Ligands: 5,5′-Bitetrazolate and 1,3-Bis(tetrazol-5-yl)triazenate—On the Borderline between Coordination and the Formation of Salt-Like Compounds" @default.
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- W2113517375 doi "https://doi.org/10.1002/chem.200702006" @default.
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