Matches in SemOpenAlex for { <https://semopenalex.org/work/W2113553502> ?p ?o ?g. }
- W2113553502 abstract "Abstract This review analyses and summarises the previous investigations on the oxidation of linseed oil and the self-heating of cotton and other materials impregnated with the oil. It discusses the composition and chemical structure of linseed oil, including its drying properties. The review describes several experimental methods used to test the propensity of the oil to induce spontaneous heating and ignition of lignocellulosic materials soaked with the oil. It covers the thermal ignition of the lignocellulosic substrates impregnated with the oil and it critically evaluates the analytical methods applied to investigate the oxidation reactions of linseed oil. Initiation of radical chains by singlet oxygen ( 1 Δ g ), and their propagation underpin the mechanism of oxidation of linseed oil, leading to the self-heating and formation of volatile organic species and higher molecular weight compounds. The review also discusses the role of metal complexes of cobalt, iron and manganese in catalysing the oxidative drying of linseed oil, summarising some kinetic parameters such as the rate constants of the peroxidation reactions. With respect to fire safety, the classical theory of self-ignition does not account for radical and catalytic reactions and appears to offer limited insights into the autoignition of lignocellulosic materials soaked with linseed oil. New theoretical and numerical treatments of oxidation of such materials need to be developed. The self-ignition induced by linseed oil is predicated on the presence of both a metal catalyst and a lignocellulosic substrate, and the absence of any prior thermal treatment of the oil, which destroys both peroxy radicals and singlet O 2 sensitisers. An overview of peroxyl chemistry included in the article will be useful to those working in areas of fire science, paint drying, indoor air quality, biofuels and lipid oxidation." @default.
- W2113553502 created "2016-06-24" @default.
- W2113553502 creator A5009961264 @default.
- W2113553502 creator A5016442925 @default.
- W2113553502 creator A5056625963 @default.
- W2113553502 creator A5076535396 @default.
- W2113553502 date "2012-09-19" @default.
- W2113553502 modified "2023-10-16" @default.
- W2113553502 title "Low temperature oxidation of linseed oil: a review" @default.
- W2113553502 cites W135787402 @default.
- W2113553502 cites W1604480167 @default.
- W2113553502 cites W1895566720 @default.
- W2113553502 cites W1964101777 @default.
- W2113553502 cites W1965220221 @default.
- W2113553502 cites W1969410195 @default.
- W2113553502 cites W1970694675 @default.
- W2113553502 cites W1972607088 @default.
- W2113553502 cites W1973506421 @default.
- W2113553502 cites W1973624036 @default.
- W2113553502 cites W1974883793 @default.
- W2113553502 cites W1975127088 @default.
- W2113553502 cites W1975767997 @default.
- W2113553502 cites W1976079566 @default.
- W2113553502 cites W1976728855 @default.
- W2113553502 cites W1976962589 @default.
- W2113553502 cites W1979098727 @default.
- W2113553502 cites W1981182593 @default.
- W2113553502 cites W1981349960 @default.
- W2113553502 cites W1981675300 @default.
- W2113553502 cites W1982015389 @default.
- W2113553502 cites W1984675432 @default.
- W2113553502 cites W1986311702 @default.
- W2113553502 cites W1988532175 @default.
- W2113553502 cites W1988663720 @default.
- W2113553502 cites W1989345052 @default.
- W2113553502 cites W1994036302 @default.
- W2113553502 cites W1995744646 @default.
- W2113553502 cites W1996204839 @default.
- W2113553502 cites W1997624269 @default.
- W2113553502 cites W1998222142 @default.
- W2113553502 cites W1998708521 @default.
- W2113553502 cites W1999101432 @default.
- W2113553502 cites W1999313192 @default.
- W2113553502 cites W2001472324 @default.
- W2113553502 cites W2001801189 @default.
- W2113553502 cites W2002925350 @default.
- W2113553502 cites W2003345498 @default.
- W2113553502 cites W2004826230 @default.
- W2113553502 cites W2005205552 @default.
- W2113553502 cites W2005407922 @default.
- W2113553502 cites W2006158336 @default.
- W2113553502 cites W2007800431 @default.
- W2113553502 cites W2008301017 @default.
- W2113553502 cites W2008899109 @default.
- W2113553502 cites W2009372105 @default.
- W2113553502 cites W2009957783 @default.
- W2113553502 cites W2011650602 @default.
- W2113553502 cites W2013592393 @default.
- W2113553502 cites W2016638797 @default.
- W2113553502 cites W2018492868 @default.
- W2113553502 cites W2019025810 @default.
- W2113553502 cites W2021092504 @default.
- W2113553502 cites W2022558510 @default.
- W2113553502 cites W2022847557 @default.
- W2113553502 cites W2024092039 @default.
- W2113553502 cites W2024488915 @default.
- W2113553502 cites W2027779710 @default.
- W2113553502 cites W2028034250 @default.
- W2113553502 cites W2028625375 @default.
- W2113553502 cites W2029724200 @default.
- W2113553502 cites W2030305590 @default.
- W2113553502 cites W2035084110 @default.
- W2113553502 cites W2035443658 @default.
- W2113553502 cites W2036251074 @default.
- W2113553502 cites W2036312778 @default.
- W2113553502 cites W2036316528 @default.
- W2113553502 cites W2037922602 @default.
- W2113553502 cites W2040323398 @default.
- W2113553502 cites W2040588290 @default.
- W2113553502 cites W2041231750 @default.
- W2113553502 cites W2043815684 @default.
- W2113553502 cites W2044951668 @default.
- W2113553502 cites W2046033679 @default.
- W2113553502 cites W2048076932 @default.
- W2113553502 cites W2049043289 @default.
- W2113553502 cites W2050976172 @default.
- W2113553502 cites W2051479152 @default.
- W2113553502 cites W2056384766 @default.
- W2113553502 cites W2056859288 @default.
- W2113553502 cites W2057049492 @default.
- W2113553502 cites W2057129789 @default.
- W2113553502 cites W2057160663 @default.
- W2113553502 cites W2057962474 @default.
- W2113553502 cites W2059851589 @default.
- W2113553502 cites W2060107506 @default.
- W2113553502 cites W2060734582 @default.
- W2113553502 cites W2062188366 @default.
- W2113553502 cites W2062802818 @default.
- W2113553502 cites W2063754775 @default.
- W2113553502 cites W2063910422 @default.