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- W2113581446 abstract "Abstract Vanadium carbide incorporated on resorcinol–formaldehyde resin carbon (V 8 C 7 @RFC) was synthesized as a novel mesoporous catalyst‐support material by pyrolysis of the resorcinol–formaldehyde resin and NaVO 3 mixture. The material’s BET surface area was 564 m 2 g −1 and thus much higher than that of 389 m 2 g −1 for the carbon powders yielded by resin carbonation. Physical characterization revealed that the supporting material possesses a mesoporous structure and Pt nanoparticles are homogeneously dispersed on the V 8 C 7 @RFC surface. Electrochemical measurements demonstrated that the V 8 C 7 ‐modified Pt catalyst exhibits a negative shift of over 100 mV in the onset potential for CO ads electrooxidation and a dramatically enhanced activity in methanol oxidation reaction. The enhancement was mainly attributed to the electronic effect between Pt and V 8 C 7 and the mesoporous structure providing ideal anchor sites for Pt dispersion." @default.
- W2113581446 created "2016-06-24" @default.
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- W2113581446 date "2014-10-01" @default.
- W2113581446 modified "2023-10-18" @default.
- W2113581446 title "Promotion of Mesoporous Vanadium Carbide Incorporated on Resorcinol-Formaldehyde Resin Carbon Composites with High-Surface-Areas on Platinum Catalysts for Methanol Electrooxidation" @default.
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- W2113581446 doi "https://doi.org/10.1002/cctc.201402478" @default.
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