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• W2113593614 abstract "Resibufogenin is a cytotoxic steroid isolated from the Chinese drug ChanSu. The biotransformation of resibufogenin by Mucor polymorphosporus afforded 22 products, and 15 of them were new. The transformation reactions involved hydroxylations at C-1β, C-5, C-7α, C-7β, C-12α, C-12β and C-16α, as well as epimerization or dehydrogenation of 3-OH. Hydroxylations at C-12α, C-12β and C-16α were the major reactions, each giving products in >5% yields, whereas the other products were obtained in fairly low yields. Some of the products showed decreased but still potent cytotoxicities. This investigation provided a useful approach to prepare new bufadienolides and most of them were difficult to obtain by chemical means." @default.
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• W2113593614 date "2005-09-01" @default.
• W2113593614 modified "2023-10-18" @default.
• W2113593614 title "New cytotoxic bufadienolides from the biotransformation of resibufogenin by Mucor polymorphosporus" @default.
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• W2113593614 doi "https://doi.org/10.1016/j.tet.2005.07.012" @default.
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